ACTIVE BPO<SUB>4</SUB> CATALYST FOR OLIGOMERIZATION OF LIGHT OLEFINS
نویسندگان
چکیده
منابع مشابه
Copolymerization of ethylene with α-olefins over highly active supported Ziegler-Natta catalyst with vanadium active component
The new highly active supported vanadium-magnesium catalyst (VMC) has been studied in α-olefin (1-butene, 1-hexene)/ ethylene copolymerization in the presence of hydrogen. Data on the effect of α-olefin/ethylene ratio in copolymerization on the content of branchings in copolymers, kinetic profile, copolymer yield, molecular weight and molecular weight distribution of copolymers have been obtain...
متن کاملPreparation and Characterization of CoMn/TiO2 Catalysts for Production of Light Olefins
A series of x(Co, Mn)/TiO2 catalysts (x=2–12wt.%) containing 25%Co and 75%Mn were prepared by the co-impregnation method. All prepared catalysts have been tested in Fischer-Tropsch synthesis for production of C2-C4 olefins. It was found that the catalyst containing 8wt.%(Co,Mn)/TiO2 is an optimal catalyst for production of C...
متن کاملNovel ruthenium-catalyst for hydroesterification of olefins with formates.
An alternative ruthenium-based catalyst for the hydroesterification of olefins with formates is reported. The good activity of our system is ensured by the use of a bidentate P,N-ligand and ruthenium dodecacarbonyl. A range of formates can be used for selective alkoxycarbonylation of aromatic olefins. In addition, the synthesis of selected aliphatic esters is realized. The proposed active ruthe...
متن کاملHomogeneous and heterogeneous oligomerization reactions of olefins with unbridged metallocene catalysts
1-Pentene, respectively 1-hexene, were reacted with 13 homogeneous metallocene catalysts to give linear oligomerization products, predominantly dimers, with selectivities above 90%. The product distributions of the codimerization reactions of 1-pentene with 1-hexene reflected a binomial behaviour. Therefore, the ratio for dimers is 1:2:1 (C10:C11:C12) while the trimers (pentadecenes up to octad...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Phosphorus Research Bulletin
سال: 2005
ISSN: 0918-4783
DOI: 10.3363/prb1992.18.0_109